CPFD Modeling to Study the Hydrodynamics of an Industrial Fluidized Bed Reactor for Alumina Chlorination

EasyChair Preprint 6699

Abstract

Aluminum is now the world's second most used metal. Since aluminum has a unique combination of appealing properties and effects, it allows for significant energy savings in many applications, such as vehicles and buildings. Although this energy-saving leads to lower CO2 emissions, the production process of aluminum still dramatically impacts the environment. The process used almost exclusively in the aluminum industry is the Hall-Héroult process with a considerable amount of carbon footprint with high energy consumption. As the best alternative, Alcoa's process (which is not industrialized yet) is based on the chlorination of processed aluminum oxide, reducing the traditional method's negative impacts. In continuation of Alcoa’s effort, this study aims to investigate the possibility of a new low carbon aluminum production process by designing an industrial fluidized bed reactor equipped with an external (due to high corrosion inside the reactor) gas-solid separation unit to handle a total of 0.6 kg/s of solid reactants and produce aluminum chloride as the main product. The research focuses on determining the best bed height based on the available reaction rates, determining the best reactor dimension to reduce particle outflow under isothermal conditions (700°C). Autodesk Inventor® and Barracuda® are used for 3D modeling of the reactor and CFD simulation for multiphase (solid-gas) reaction, respectively. Although results have shown that the bed aspect ratio (H/D; H- bed Height and D- bed Diameter) does not affect the reaction, it highly affects the reactor’s hydrodynamics and particle outflow. The final design shows the best hydrodynamics belongs to bed aspect ratio equal to 2.

Keyphrases: Alumina Chlorination, Bubbling regime, CPFD simulation, fluidized bed reactor, reactor design

@booklet{EasyChair:6699,
  author    = {Zahir Barahmand and Chameera Jayarathna and Chandana Ratnayake},
  title     = {CPFD Modeling to Study the Hydrodynamics of an Industrial Fluidized Bed Reactor for Alumina Chlorination},
  howpublished = {EasyChair Preprint 6699},
  year      = {EasyChair, 2021}}